Silicon is recognized as a promising material for next-generation lithium-ion batteries, offering a storage capacity approximately 10 times higher than that of conventional carbon-based electrodes. Despite extensive research, the practical application of silicon-based electrodes remains constrained by a significant loss of capacity. This issue is primarily attributed to cracks caused by substantial swelling during cycling, which places an extremely high burden on the mechanical stability and structural integrity of the electrode [1]. Mechanical stresses, induced by chemical reactions as lithium ions diffuse into silicon during cycling, nucleate, and drive cracks that hinder further ion transport, ultimately leading to capacity loss. The lithiation of silicon is a complex electro-chemo-mechanical process that is not yet fully understood. Our high-fidelity phase-field computational models incorporate key structural features across length and time scales while capturing some of the dominant physical phenomena that dictate battery efficiency. The simulation results are compared with findings reported in the literature, including observations of deforming silicon particles in real Si-based battery cells under cycling, cf. [2]. While the striking agreement between simulations and experiments is promising, it also highlights a need for a deeper understanding of the lithium-ion diffusion process in silicon, particularly the multiple material phase changes that occur between lithium and silicon. [1] He, Huang, Wang, Mizota, Liu, Hou (2021). Energy Fuels 35 944-64 [2] Taiwo, Paz-García, Hall, Heenan, Finegan, Mokso, Villanueva-Pérez, Patera, Brett, Shearing (2017). Journal of Power Sources 342 904-912